Synthesis and thermal properties of 4,4′-bipyridine adducts of Mn(II), Co(II), Ni(II) and Cu(II) monochloroacetate

被引：18

作者：

Czakis-Sulikowska, D ^{[1
]}

Czylkowska, A ^{[1
]}

Radwanska-Doczekalska, J ^{[1
]}

机构：

[1] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2000年 / 63卷 / 02期

关键词：

4,4 '-bipyridine complexes; mass spectrometry; monochloroacetate; thermal decomposition; VIS-IR spectra;

D O I：

10.1023/A:1010188325149

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The complexes with the empirical formula M(4-bipy)(ClCH2COO)(2). nH(2)O (where: 4-bipy=4,4'-bipyridine, L=ClCH2COO-, M(II)=Mn, Co, Ni, Cu) were prepared and characterized via the IR and electronic (VIS) spectra and conductivity measurements. Thermal decomposition of these compounds was studied. During heating in air dehydration processes occur. The anhydrous compounds decompose at high temperature to oxides. The principal volatile mass fragments correspond to: H2O, CO2, CH3Cl, HCl, Cl-2 and other.

引用

页码：387 / 395

页数：9

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