Molar volume, molar refraction, and isentropic compressibility changes of mixing at 25°C for the system ethanol plus methanol plus dibutyl ether

被引:18
作者
Arce, A [1 ]
Rodil, E [1 ]
Soto, A [1 ]
机构
[1] Univ Santiago de Compostela, Dept Chem Engn, E-15706 Santiago, Spain
关键词
physical properties; ethanol; methanol; dibutyl ether (DBE);
D O I
10.1023/A:1022611228690
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The densities, refractive indexes, and sound velocities for mixtures of ethanol + methanol + dibutyl ether at 25 degrees C and atmospheric pressure, were determined and used to calculate molar volumes, molar refractions, and isentropic compressibilities. The excess molar volumes and the deviations of molar refractions and isentropic compressibilities from mole fraction and volume fraction averages, respectively, of these properties of the pure components were satisfactorily correlated with the composition data by means of the Redlich-Kister polynomial.
引用
收藏
页码:911 / 923
页数:13
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