Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity

被引：81

作者：

Carta, Mariolino ^{[1
]}

Msayib, Kadhurn J. ^{[1
]}

Budd, Peter M. ^{[2
]}

McKeown, Neil B. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 13期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ol800573m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of novel spirobisindane-based monomers for the preparation of polymers of intrinsic microporosity (PIMs) with bulky, rigid substituents is described. Polymers derived from monomers containing spiro-linked fluorene substituents display enhanced solubility and microporosity due to additional frustration of packing in the solid state.

引用

页码：2641 / 2643

页数：3

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