The origin of solvent-controlled supramolecular chirality switching in a Bis(Zinc porphyrin) system

被引：80

作者：

Borovkov, VV ^{[1
]}

Hembury, GA ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] JST, ICORP, Entropy Control Project, Toyonaka, Osaka 5600085, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 43期

关键词：

chirality; circular dichroism; porphyrinoids; solvent effects; supramolecular chemistry;

D O I：

10.1002/anie.200352493

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inducing chirality: The supramolecular interaction of achiral bis(zinc porphyrin) with enantiopure amino acid derivatives in different solvents results in chirality induction. The sign and degree of the circular dichroims is controlled by the solvent polarity (see picture).

引用

页码：5310 / 5314

页数：5

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