Simple, tunable aziridination catalysts based on poly(pyrazolyl)borate-copper complexes

被引：30

作者：

Handy, ST ^{[1
]}

Czopp, M ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 10期

关键词：

D O I：

10.1021/ol015539w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The in situ generation of a copper-poly(pyrazolyl)borate complex from copper chloride and a sodium poly(pyrazolyl)borate salt results in a catalyst that is effective for the aziridination of olefins, A significant influence of the combination of the starting copper oxidation state and the hapticity of the poly(pyrazolyl)borate ligand on the efficiency of the reaction has been observed.

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页码：1423 / 1425

页数：3

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