A direct synthesis of mesoporous carbons with bicontinuous pore morphology from crude plant material by hydrothermal carbonization

被引:424
作者
Titirici, Maria M.
Thomas, Arne
Yu, Shu-Hong
Mueller, Jens-O.
Antonietti, Markus
机构
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany
[2] Univ Sci & Technol China, Chinese Acad Sci, Struct Res Lab,Hefei Natl Lab Phys Sci Microsc, Dept Mat Sci & Engn,Div Nanomat & Chem, Hefei 230026, Peoples R China
[3] Fritz Haber Inst, Max Planck Soc, D-14195 Berlin, Germany
关键词
D O I
10.1021/cm0707408
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrothermal carbonization is a convenient way to convert biomass at rather moderate conditions into carbonaceous nanostructures, here, mesoporous network structures. A structural view on the micro- and nanoscale reveals interesting features defining the usefulness and application possibilities of the resulting carbonaceous materials as supports and for sorption purposes. Whereas weakly connected plant tissues result in good yields of carbon nanoparticles with very small sizes where the porosity is mainly interstitial, "hard" plant tissue is structurally transformed into a carbon replica with a rather well-defined, bicontinuous mesopore structure.
引用
收藏
页码:4205 / 4212
页数:8
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