Convenient synthesis of [3]catenane by olefin metathesis dimerizations

被引:52
作者
Iwamoto, H
Itoh, K
Nagamiya, H
Fukazawa, Y [1 ]
机构
[1] Hiroshima Univ, Grad Sch Sci, Dept Chem, Higashihiroshima 7398526, Japan
[2] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
关键词
ring-closing metathesis; olefin metathesis dimerization; 3]catenane;
D O I
10.1016/S0040-4039(03)01424-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[3]Catenane 5a and 5b were synthesized conveniently by olefin metathesis dimerization of pseudorotaxanes 3a and 3b. The yields of 5a and 5b were influenced by concentrations of 3a and 3b, and a ring size of a center wheel of [3]catenane. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5773 / 5776
页数:4
相关论文
共 51 条
[1]   Interlocked and intertwined structures and superstructures [J].
Amabilino, DB ;
Stoddart, JF .
CHEMICAL REVIEWS, 1995, 95 (08) :2725-2828
[2]  
Amabilino DB, 1998, CHEM-EUR J, V4, P460
[3]   Rotaxanes incorporating two different coordinating units in their thread:: Synthesis and electrochemically and photochemically induced molecular motions [J].
Armaroli, N ;
Balzani, V ;
Collin, JP ;
Gaviña, P ;
Sauvage, JP ;
Ventura, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4397-4408
[4]  
Ashton PR, 2000, EUR J ORG CHEM, V2000, P1121, DOI 10.1002/1099-0690(200004)2000:7<1121::AID-EJOC1121>3.0.CO
[5]  
2-3
[6]  
Ashton PR, 1996, CHEM-EUR J, V2, P729
[7]  
Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO
[8]  
2-X
[9]   Molecular machines [J].
Balzani, V ;
Gómez-López, M ;
Stoddart, JF .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) :405-414
[10]  
Ben-Efraim D.A., 1970, J AM CHEM SOC, V92, P2133