Triphenylamine/Tetracyanobutadiene-Based D-A-D π-Conjugated Systems as Molecular Donors for Organic Solar Cells

被引:140
作者
Leliege, Antoine [1 ]
Blanchard, Philippe [1 ]
Rousseau, Theodulf [1 ]
Roncali, Jean [1 ]
机构
[1] Univ Angers, CNRS, MOLTECH Anjou, Linear Conjugated Syst Grp, F-49045 Angers, France
关键词
INTERNAL CHARGE-TRANSFER; HIGHLY EFFICIENT; OLIGOTHIOPHENES;
D O I
10.1021/ol201002j
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Thlophene-based D-A-D pi-conjugated systems containing triphenylamine end groups connected to a 1,1,4,4-tetracyanobuta-1,3-diene acceptor by oligothiophene chains of variable length have been synthesized. These compounds show Interesting light-harvesting properties and low-lying HOMO levels. Preliminary results on bilayer heterojunction solar cells with C-60 as acceptor show power conversion efficiency higher than 1.0%.
引用
收藏
页码:3098 / 3101
页数:4
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