Raman spectroscopic study of ionic association in molten LaCl3 and molten CsCl-NaCl mixtures

被引：4

作者：

Iwadate, Y

Matsuura, H

Kajinami, A

Takase, K

Ohtori, N

Umesaki, N

Kofuji, H

Myochin, M

机构：

[1] Chiba Univ, Grad Sch Sci & Technol, Inage Ku, Chiba 2638522, Japan

[2] Tokyo Inst Technol, Nucl Reactors Res Lab, Meguro Ku, Tokyo 1528550, Japan

[3] Kobe Univ, Fac Engn, Dept Appl Chem, Nada Ku, Kobe, Hyogo 6578501, Japan

[4] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[5] Japan Synchrotron Radiat Res Inst, Mikazuki, Hyogo 6795198, Japan

[6] Japan Nucl Cycle Dev Inst, Tokai, Ibaraki 3191194, Japan

来源：

ELECTROCHEMISTRY | 2005年 / 73卷 / 11期

关键词：

Raman spectra; ionic association; melt; LaCl3; CsCl-NaCl;

D O I：

10.5796/electrochemistry.73.936

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 [应用化学];

摘要：

The structures of molten LaCl3 and molten CsCl-NaCl mixtures were studied by Raman spectroscopy. Ionic association in these melts was discussed according to the information of vibrational modes. Complex species of the octahedral type, LaCl63-, was formed in the melt and no association was observed in the molten CsCl-NaCl system.

引用

页码：936 / 938

页数：3

共 19 条

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Raman spectroscopic study of molten SmCl3-ACl systems (A = Li, Na, K) [J].