Preparation of activated carbon from date stones by microwave induced chemical activation: Application for methylene blue adsorption

被引:133
作者
Foo, K. Y. [1 ]
Hameed, B. H. [1 ]
机构
[1] Univ Sci Malaysia, Sch Chem Engn, Nibong Tebal 14300, Penang, Malaysia
关键词
Activated carbon; Adsorption; Date stone; Methylene blue; Microwave; BASIC DYE; EQUILIBRIUM; REMOVAL; WASTE;
D O I
10.1016/j.cej.2011.02.068
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work, a low cost activated carbon was prepared from date stones char (DSAC) under microwave induced KOH chemical activation. The activation step was performed at the microwave input power of 600W and irradiation time of 8 min. Porous texture, surface and functional characteristics were analyzed by N-2 adsorption, scanning electron microscopy, Fourier transform infrared spectroscopy, and equilibrium studies. Adsorption isotherm was fitted by Freundlich, Langmuir and Temkin isotherm models. Result showed that the monolayer adsorption capacity of the DSAC for methylene blue was 316.11 mg/g, while the BET surface area, Langmuir surface area and total pore volume of DSAC were 856 m(2)/g, 1275 m(2)/g and 0.4680 cm(3)/g, respectively. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:338 / 341
页数:4
相关论文
共 18 条
[1]   Removal of lead(II) from wastewater by activated carbon developed from Tamarind wood by zinc chloride activation [J].
Acharya, Jyotikusum ;
Sahu, J. N. ;
Mohanty, C. R. ;
Meikap, B. C. .
CHEMICAL ENGINEERING JOURNAL, 2009, 149 (1-3) :249-262
[2]   Adsorption of basic dye onto activated carbon prepared from durian shell: Studies of adsorption equilibrium and kinetics [J].
Chandra, Thio Christine ;
Mirna, M. M. ;
Sudaryanto, Y. ;
Ismadji, S. .
CHEMICAL ENGINEERING JOURNAL, 2007, 127 (1-3) :121-129
[3]   Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation [J].
Deng, Hui ;
Li, Guoxue ;
Yang, Hongbing ;
Tang, Jiping ;
Tang, Jiangyun .
CHEMICAL ENGINEERING JOURNAL, 2010, 163 (03) :373-381
[4]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[5]   Adsorption studies of basic dye on activated carbon derived from agricultural waste:: Hevea brasiliensis seed coat [J].
Hameed, B. H. ;
Daud, F. B. M. .
CHEMICAL ENGINEERING JOURNAL, 2008, 139 (01) :48-55
[6]   Adsorption of dyes onto carbonaceous materials produced from coffee grounds by microwave treatment [J].
Hirata, M ;
Kawasaki, N ;
Nakamura, T ;
Matsumoto, K ;
Kabayama, M ;
Tamura, T ;
Tanada, S .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 254 (01) :17-22
[7]   Influence of microwave irradiation on a polyesterification reaction [J].
Komorowska, M. ;
Stefanidis, G. D. ;
Van Gerven, T. ;
Stankiewicz, A. I. .
CHEMICAL ENGINEERING JOURNAL, 2009, 155 (03) :859-866
[8]   THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. [J].
Langmuir, Irving .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1918, 40 :1361-1403
[9]   Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation [J].
Liou, Tzong-Horng .
CHEMICAL ENGINEERING JOURNAL, 2010, 158 (02) :129-142
[10]   Modification of bamboo-based activated carbon using microwave radiation and its effects on the adsorption of methylene blue [J].
Liu, Qing-Song ;
Zheng, Tong ;
Li, Nan ;
Wang, Peng ;
Abulikemu, Gulizhaer .
APPLIED SURFACE SCIENCE, 2010, 256 (10) :3309-3315