Fourier transform infrared spectroscopic study of thermal degradation of sugar cane bagasse

被引:139
作者
Bilba, K
Ouensanga, A
机构
[1] Grp. Rech. Energies Renouvelables, U. F. R. Sci. Exactes et Naturelles, Univ. des Antilles et de la Guyane, 97157 Pointe à Pitre Cedex
关键词
bagasse; carbonization; Fourier transform infrared spectroscopy; sugar cane; thermal degradation;
D O I
10.1016/S0165-2370(96)00952-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Thermal degradation of sugar cane bagasse has been studied between 200 and 800 degrees C under a nitrogen gas flow. Different experimental parameters of the pyrolysis have been investigated, including holding temperature, time duration of pyrolysis, and heating rate. The solid residues obtained were then analyzed by classical elemental analysis and Fourier transform infrared (FTIR) spectroscopy. The most important structure modifications appeared between 300 and 400 degrees C, and they are characterized by the decrease of intensities of C-O and C=C bands and the formation of alkyl bands. The thermal degradation of bagasse is marked by dehydration and the formation of CO and CO2 molecules. The carbonization is characterized by the disappearance of chemical bonds and the formation of low molecular weight compounds leading to a char consisting essentially of carbon, hydrogen and mineral oxides.
引用
收藏
页码:61 / 73
页数:13
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