Effect of operational conditions during n-hexane isomerization over platinum on tungsten-oxide-promoted zirconia

被引：11

作者：

Comelli, RA ^{[1
]}

Canavese, SA ^{[1
]}

Fígoli, NS ^{[1
]}

机构：

[1] Inst Invest Catalisis & Petroquim, INCAPE, FIQ, UNL,CONICET, RA-3000 Santa Fe, Argentina

来源：

CATALYSIS LETTERS | 1998年 / 55卷 / 3-4期

关键词：

platinum on tungsten-oxide-promoted zirconia; isomerization; operational conditions; n-hexane;

D O I：

10.1023/A:1019063819189

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of total pressure, temperature and H-2:N-2 molar ratio on both catalytic activity and selectivity during n-hexane isomerization over platinum impregnated on tungsten-oxide-promoted zirconia was studied. It was found that the increase in pressure up to 6 kg cm(-2) increases catalytic activity. The higher the temperature, the larger the catalytic activity. Selectivity to isomers remains practically constant, only decreasing when temperature is increased above 225 degrees C. In the absence of hydrogen, a rapid deactivation is observed as well as a different product distribution.

引用

页码：177 / 182

页数：6

共 30 条

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