Synthesis of vanadium oxide, V6O13 hollow-flowers materials and their application in electrochemical supercapacitors

被引:54
作者
Huang, Zhiyong [1 ]
Zeng, Hongmei [1 ]
Xue, Li [1 ]
Zhou, Xiangge [1 ]
Zhao, Yan [1 ,2 ]
Lai, Qiongyu [1 ]
机构
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Peoples R China
关键词
Vanadium oxide; Hollow-flowers; Mechanism; Supercapacitors; LITHIUM-ION BATTERIES; TEMPLATE-FREE SYNTHESIS; INTERCALATION PROPERTIES; HYDROTHERMAL SYNTHESIS; CAPACITIVE PROPERTIES; COMPOSITE ELECTRODES; CATHODE MATERIALS; RUTHENIUM OXIDE; BEHAVIOR; DEPOSITION;
D O I
10.1016/j.jallcom.2011.08.042
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hollow flowers-like V6O13 with an average size of 3 mu m was successfully synthesized via a facile sol-hydrothermal approach in a short time. The surface composition, crystalline components and morphology of V6O13 were characterized by X-ray photoelectron spectra (XPS), powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) measurements, respectively. An intercalating-exfoliatingself- assembly model was proposed to explain the formation process of hollow-flower structure based on experimental results. The obtained hollow flowers-like V6O13 exhibits high specific capacitance, good cyclability and low resistance as revealed by analysis of cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS). Experimental results also indicate that hollow flowers-like V6O13 can deliver a capacitance of 417 F g(-1) at a scan rate of 5 mV s(-1). This value would decrease to 400 F g(-1) after 1000 cycles in potential range from 0 to 0.8 V versus saturated calomel electrode (SCE) in 1 mol L-1 NaNO3 aqueous electrolyte at pH of 2. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:10080 / 10085
页数:6
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