Rotational relaxation of nitrogen in helium

被引：13

作者：

Belikov, AE ^{[1
]}

Sharafutdinov, RG ^{[1
]}

Storozhev, AV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST CHEM KINET & COMBUST,NOVOSIBIRSK 630090,RUSSIA

来源：

CHEMICAL PHYSICS | 1996年 / 213卷 / 1-3期

关键词：

D O I：

10.1016/S0301-0104(96)00275-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rotational level populations of N-2 have been measured in free jets of He + N-2 mixtures by an electron beam technique. The experimental data are compared with kinetic calculations, based on theoretical state-to-state rate constants, obtained by the IOS method with an M3SV potential energy surface. Reasonable agreement of the data substantiates the IOS method down to low (approximate to 10 K) temperatures. Other available calculations of rotational relaxation times are compared with the present experimental data.

引用

页码：319 / 331

页数：13

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