Recent advances in direct formic acid fuel cells (DFAFC)

被引：1044

作者：

Yu, Xingwen ^{[1
]}

Pickup, Peter G. ^{[1
]}

机构：

[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

来源：

JOURNAL OF POWER SOURCES | 2008年 / 182卷 / 01期

关键词：

direct formic acid fuel cell (DFAFC); formic acid oxidation; catalyst; crossover; cell configuration;

D O I：

10.1016/j.jpowsour.2008.03.075

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polymer electrolyte membrane-based direct formic acid fuel cells (DFAFC) have been investigated for about a decade, and are now becoming an important area of portable power system research. DFAFCs have the advantages of high electromotive force (theoretical open circuit potential 1.48V), limited fuel crossover, and reasonable power densities at low temperatures. This paper provides a review of recent advances in DFAFCs, mainly focussing on the anodic catalysts for the electro-oxidation of formic acid. The fundamental DFAFC chemistry, formic acid crossover through Nafion (R) membranes, and DFAFC configuration development are also presented. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：124 / 132

页数：9

共 81 条

[1] Recent advances in fuel cell technology and its applications [J].

Acres, GJK .

JOURNAL OF POWER SOURCES, 2001, 100 (1-2) :60-66

[2] Intermetallic PtPb nanoparticles prepared by sodium naphthalide reduction of metal-organic precursors:: Electrocatalytic oxidation of formic acid [J].

Alden, Laif R. ;

Han, Daniel K. ;

Matsumoto, Futoshi ;

Abruna, Hector D. ;

DiSalvo, Francis J. .

CHEMISTRY OF MATERIALS, 2006, 18 (23) :5591-5596

[3] Synthesis, characterization, and electrocatalytic activity of PtPb nanoparticles prepared by two synthetic approaches [J].

Alden, Laif R. ;

Roychowdhury, Chandrani ;

Matsumoto, Futoshi ;

Han, Daniel K. ;

Zeldovich, Varvara B. ;

Abruna, Hector D. ;

DiSalvo, Francis J. .

LANGMUIR, 2006, 22 (25) :10465-10471

[4] The electro-oxidation of formic acid on Pt-Pd single crystal bimetallic surfaces [J].

Arenz, M ;

Stamenkovic, V ;

Schmidt, TJ ;

Wandelt, K ;

Ross, PN ;

Markovic, NM .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (19) :4242-4251

[5] Surface (electro-)chemistry on Pt(111) modified by a Pseudomorphic Pd monolayer [J].

Arenz, M ;

Stamenkovic, V ;

Ross, PN ;

Markovic, NM .

SURFACE SCIENCE, 2004, 573 (01) :57-66

[6]

Aricò AS, 2001, FUEL CELLS, V1, P133

[7] Formic acid oxidation on ultrathin Pd films on Au(hkl) and Pt(hkl) electrodes [J].

Baldauf, M ;

Kolb, DM .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (27) :11375-11381

[8] OXIDATION OF FORMIC-ACID AT NOBLE-METAL ELECTRODES PART .3. INTERMEDIATES AND MECHANISM ON PLATINUM-ELECTRODES [J].

CAPON, A ;

PARSONS, R .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1973, 45 (02) :205-231

[9] OXIDATION OF FORMIC-ACID ON NOBLE-METAL ELECTRODES .2. COMPARISON OF BEHAVIOR OF PURE ELECTRODES [J].

CAPON, A ;

PARSONS, R .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1973, 44 (02) :239-254

[10] OXIDATION OF FORMIC-ACID AT NOBLE-METAL ELECTRODES .1. REVIEW OF PREVIOUS WORK [J].

CAPON, A ;

PARSONS, R .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1973, 44 (01) :1-7

← 1 2 3 4 5 6 7 8 9 →