Ladder-type phthalocyanine conductor, [PXX][Co(Pc)(CN)2] (PXX = peri-xanthenoxanthene, Co(Pc)(CN)2 = dicyano(phthalocyaninato)cobalt(III))

被引:26
作者
Takano, S [1 ]
Naito, T [1 ]
Inabe, T [1 ]
机构
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
关键词
D O I
10.1246/cl.1998.1249
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrochemical oxidation of PXX and [Co(Pc)(CN)(2)](-) in acetonitrile gives a highly conducting crystal containing two-leg ladder chains of the partially oxidized Co(Pc)(CN)(2) units. The doubling of the one-dimensional chains makes the electrical properties quite different from those in the single chain conductor.
引用
收藏
页码:1249 / 1250
页数:2
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