Compact-designed supercapacitors using free-standing single-walled carbon nanotube films

被引:314
作者
Niu, Zhiqiang [1 ,3 ]
Zhou, Weiya [1 ]
Chen, Jun [2 ]
Feng, Guoxing [1 ,3 ]
Li, Hong [1 ]
Ma, Wenjun [1 ,3 ]
Li, Jinzhu [1 ,3 ]
Dong, Haibo [1 ,3 ]
Ren, Yan [1 ,3 ]
Zhao, Duan [1 ,3 ]
Xie, Sishen [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
[2] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia
[3] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
DOUBLE-LAYER CAPACITORS; ELECTROCHEMICAL CHARACTERIZATION; HIGH-POWER; ENERGY-STORAGE; DIRECT GROWTH; ELECTRODES; DENSITY; ARRAYS;
D O I
10.1039/c0ee00261e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We reported the realization of assembling compact-designed supercapacitors using large-scaled free-standing and flexible single-walled carbon nanotube (SWCNT) films as both anode and cathode. A prototype of the processing procedures was developed to obtain the uniform spreading of the SWCNT films onto the separators serving as both electrodes and charge collectors without metallic current collectors, leading to a simplified and lightweight architecture. The area of SWCNT film on a separator can be scaled up and its thickness can be extended. High energy and power densities (43.7 Wh kg(-1) and 197.3 kW kg(-1), respectively) were achieved from the prepared SWCNT film-based compact-designed supercapacitors with small equivalent series resistance. The specific capacitance of this kind of compact-designed SWCNT film supercapacitor is about 35 F g(-1). These results clearly show the potential application of free-standing SWCNT film in compact-designed supercapacitor with enhanced performance and significantly improved energy and power densities.
引用
收藏
页码:1440 / 1446
页数:7
相关论文
共 42 条
[1]  
Ajayan PM, 2000, ADV MATER, V12, P750, DOI 10.1002/(SICI)1521-4095(200005)12:10<750::AID-ADMA750>3.0.CO
[2]  
2-6
[3]  
An KH, 2001, ADV FUNCT MATER, V11, P387, DOI 10.1002/1616-3028(200110)11:5<387::AID-ADFM387>3.0.CO
[4]  
2-G
[5]  
An KH, 2001, ADV MATER, V13, P497, DOI 10.1002/1521-4095(200104)13:7<497::AID-ADMA497>3.3.CO
[6]  
2-8
[7]   Electrochemical characterization of single-walled carbon nanotube electrodes [J].
Barisci, JN ;
Wallace, GG ;
Baughman, RH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (12) :4580-4583
[8]   Electrochemical properties of single-wall carbon nanotube electrodes [J].
Barisci, JN ;
Wallace, GG ;
Chattopadhyay, D ;
Papadimitrakopoulos, F ;
Baughman, RH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (09) :E409-E415
[9]   Carbon nanotubes - the route toward applications [J].
Baughman, RH ;
Zakhidov, AA ;
de Heer, WA .
SCIENCE, 2002, 297 (5582) :787-792
[10]   Electrochemical characterization of carbon nanotubes as electrode in electrochemical double-layer capacitors [J].
Chen, JH ;
Li, WZ ;
Wang, DZ ;
Yang, SX ;
Wen, JG ;
Ren, ZF .
CARBON, 2002, 40 (08) :1193-1197