Molybdenum(V) chloromonophosphates with a layer structure:: AMoOPO4Cl (A = K, Rb)

被引：13

作者：

Borel, MM ^{[1
]}

Leclaire, A ^{[1
]}

Chardon, J ^{[1
]}

Provost, J ^{[1
]}

Raveau, B ^{[1
]}

机构：

[1] Inst Sci Mat & Rayonnement, Lab CRISMAT, CNRS, UMR 6508, F-14050 Caen, France

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1998年 / 137卷 / 02期

关键词：

D O I：

10.1006/jssc.1997.7703

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new pentavalent molybdenum chloromonophosphates, KMoOPO4Cl and RbMoOPO4Cl, have been synthesized. They crystallize in the p4/nmm space group with a = b = 6.4340(5) and c = 7.2715(9) Angstrom for the potassium compound and a = b = 6.4551(8) and c = 7.4612(8) Angstrom for the rubidium compound. Their original structure consists of [MoPO5Cl](infinity), layers parallel to (001), whose cohesion is ensured by K+ or Rb+ ions. The chloride ions and the alkali metal cations form a puckered rock salt layer. (C) 1998 Academic Press.

引用

页码：214 / 217

页数：4

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