Synthesis, structure and magnetic properties of a trinuclear [MnIIIMnII2] single-molecule magnet

被引:43
作者
Scott, RTW
Parsons, S
Murugesu, M
Wernsdorfer, W
Christou, G
Brechin, EK
机构
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[3] CNRS, Lab Louis Neel, F-38042 Grenoble, France
关键词
D O I
10.1039/b501504a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ferromagnetic exchange between the three Mn ions in the complex [Mn-3(Hcht)(2)(bpy)(4)](ClO4)(3) leads to a spin ground state of S = 7; single crystal studies reveal the temperature and sweep rate dependent hysteresis loops expected for a single-molecule magnet.
引用
收藏
页码:2083 / 2085
页数:3
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