Aerobic oxidation of alcohol in aqueous solution catalyzed by gold

被引：44

作者：

Li, Huanrong ^{[1
]}

Guan, Bingtao ^{[1
]}

Wang, Wenjin ^{[2
]}

Xing, Dong ^{[2
]}

Fang, Zhao ^{[1
]}

Wan, Xiaobing ^{[1
]}

Yang, Liping ^{[2
]}

Shi, Zhangjie ^{[1
,3
]}

机构：

[1] Peking Univ, Green Chem Ctr, Coll Chem, Minist Educ,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China

[3] Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON | 2007年 / 63卷 / 35期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tet.2007.05.117

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The heterogeneous oxidation catalyzed by supported gold nanoparticles has been relatively well studied. In comparison, the oxidation of alcohols catalyzed by ligand- supported gold complexes was rarely reported. Herein a general method is demonstrated to oxidize secondary and primary benzyl and allylic alcohols to carbonyl compounds via Au(I) catalyzed reaction in air and water. Primary mechanistic studies indicated that the catalytic pathway is different from those catalyzed by solid- supported gold nanoparticles. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：8430 / 8434

页数：5

共 60 条

[1] A collaborative effect between gold and a support induces the selective oxidation of alcohols
Abad, A
Concepción, P
Corma, A
García, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (26) : 4066 - 4069
[2] Gold-catalyzed reactions of 2-alkynyl-phenylamines with α,β-enones
Alfonsi, M
Arcadi, A
Aschi, M
Bianchi, G
Marinelli, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (06) : 2265 - 2273
[3] Recent applications of gold catalysis in organic synthesis
Arcadi, A
Di Giuseppe, S
[J]. CURRENT ORGANIC CHEMISTRY, 2004, 8 (09) : 795 - 812
[4] Arcadi A, 2001, ADV SYNTH CATAL, V343, P443, DOI 10.1002/1615-4169(200107)343:5<443::AID-ADSC443>3.3.CO
[5] 2-R
[6] AuCl3-catalyzed benzannulation:: Synthesis of naphthyl ketone derivatives from o-alkynylbenzaldehydes with alkynes
Asao, N
Takahashi, K
Lee, S
Kasahara, T
Yamamoto, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) : 12650 - 12651
[7] Application of gold catalysts to selective liquid phase oxidation
Biella, S
Castiglioni, GL
Fumagalli, C
Prati, L
Rossi, M
[J]. CATALYSIS TODAY, 2002, 72 (1-2) : 43 - 49
[8] A homogeneous catalyst for selective O2 oxidation at ambient temperature.: Diversity-based discovery and mechanistic investigation of thioether-oxidation by the Au(III)Cl2NO3(thioether)/O2 system
Boring, E
Geletii, YV
Hill, CL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) : 1625 - 1635
[9] Solvent-free selective oxidation of benzyl alcohol by molecular oxygen over uranium oxide supported nano-gold catalyst for the production of chlorine-free benzaldehyde
Choudhary, Vasant R.
Jha, Rani
Jana, Prabhas
[J]. GREEN CHEMISTRY, 2007, 9 (03) : 267 - 272
[10] Reaction of gold(III) oxo complexes with alkenes.: Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6].: Crystal structure of [Au(bipyip)(η2-CH2=CHPh)][PF6] (bipyip=6-isopropyl-2,2′-bipyridine)
Cinellu, MA
Minghetti, G
Stoccoro, S
Zucca, A
Manassero, M
[J]. CHEMICAL COMMUNICATIONS, 2004, (14) : 1618 - 1619

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