Rapid, room-temperature synthesis of amorphous selenium/protein composites using Capsicum annuum L extract

被引:138
作者
Li, Shikuo [1 ]
Shen, Yuhua [1 ]
Xie, Anjian [1 ]
Yu, Xuerong [1 ]
Zhang, Xiuzhen [1 ]
Yang, Liangbao [1 ]
Li, Chuanhao [1 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Hefei 230039, Peoples R China
关键词
D O I
10.1088/0957-4484/18/40/405101
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We describe the formation of amorphous selenium (alpha- Se)/protein compositesusing Capsicum annuum L extract to reduce selenium ions (SeO32-) at room temperature. The reaction occurs rapidly and the process is simple and easy to handle. A protein with a molecular weight of 30 kDa extracted from Capsicum annuum L not only reduces the SeO32- ions to Se-0, but also controls the nucleation and growth of Se0, and even participates in the formation of alpha-Se/ protein composites. The size and shell thickness of the a- Se/ protein composites increases with high Capsicum annuum L extract concentration, and decreases with low reaction solution pH. The results suggest that this eco- friendly, biogenic synthesis strategy could be widely used for preparing inorganic/organic biocomposites. In addition, we also discuss the possible mechanism of the reduction of SeO32- ions by Capsicum annuum L extract.
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页数:9
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