Swine manure/Crude glycerol co-liquefaction: Physical properties and chemical analysis of bio-oil product

被引:51
作者
Xiu, Shuangning [1 ]
Shahbazi, Abolghasem [1 ]
Shirley, Vestel B. [1 ]
Wang, Lijun [1 ]
机构
[1] N Carolina Agr & Tech State Univ, Biol Engn Program, Dept Nat Resource & Environm Design, Greensboro, NC USA
关键词
Bio-oil; Swine manure; Crude glycerol; Liquefaction; GC-MS; BIOMASS SAMPLES; AUGER REACTOR; PYROLYSIS; WOOD;
D O I
10.1016/j.biortech.2010.08.026
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The aim of this work was to investigate the principal structural and physico-chemical changes of bio-oils associated with liquefaction of swine manure with crude glycerol and its key fraction, free fatty acids. Bio-oils have been obtained from liquefaction processes at 340 degrees C. They were subjected to various physico-chemical characterization methods. FTIR data indicated a reduction in aliphatic structures and an increase in more oxidized and, probably, more polycondensed aromatic components resulting from the addition of crude glycerol to swine manure. GC-MS data indicated that the addition of crude glycerol facilitated the esterification reaction in sub-critical water to convert organic acids contained in bio-oil into various kinds of esters. The dynamic viscosity of bio-oil decreased dramatically by adding crude glycerol into the swine manure. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1928 / 1932
页数:5
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