A new synthesis of π-electron conjngated phosphonates and phosphonic bis(diethylamides) and their SHG activities

被引：67

作者：

Ogawa, T

Usuki, N

Ono, N

机构：

[1] Ehime Univ, Fac Sci, Dept Chem, Matsuyama, Ehime 790, Japan

[2] Kyushu Univ, Inst Fundamental Res Organ Chem, Fukuoka 81281, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 17期

关键词：

D O I：

10.1039/a709082j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of vinylic and arylic phosphonates and phosphonic bis(diethylamides) were prepared by copper promoted substitution of the corresponding bromides. These pi-electron conjugated phosphonates and phosphonic bis(diethylamides) were investigated to elucidate their optical and second harmonic generation (SHG) properties; it was found that diphenyl 2-(4-dimethylaminophenyl)ethenylphosphonate exhibited strong SHG activity, the efficiency being 13 times greater than that of urea.

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页码：2953 / 2958

页数：6

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