Germylenes and germyl cations with the 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl ligand

被引：54

作者：

Schmidt, H ^{[1
]}

Keitemeyer, S ^{[1
]}

Neumann, B ^{[1
]}

Stammler, HG ^{[1
]}

Schoeller, WW ^{[1
]}

Jutzi, P ^{[1
]}

机构：

[1] Univ Bielefeld, Fac Chem, D-33615 Bielefeld, Germany

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 11期

关键词：

D O I：

10.1021/om980156w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 2,4-di-tert-butyl-6-(N,N-dimethylaminomethyl)phenyl (Mamx) ligand allows the synthesis of the germylenes MamxGeCl (I), Mamx(2)Ge (2), Mamx(Tip)Ge (3; Tip = 2,4,6-iPr(3)C(6)H(2)), MamxGeN(3) (4), MamxGeN(SiMe3)(2) (5), and MamxGe[Fe(CO)(2)Cp*] (6), which are all stabilized by coordination of the amino side chain. Reactions of 2 and 3 with Mel yield the ionic compounds Mamx(Tip)(Me)Ge+I-(7) and Mamx(2)(Me)Ge+I- (8), respectively; the X-ray crystal structure of 7 shows a trigonal-planar coordination at the Ge center and a nearly perpendicular Ge-N bond.

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页码：2149 / 2151

页数：3

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