New complexes [CpFe(DPPE)thiophenes]PF6

被引：8

作者：

Diaz, C

Leal, C

机构：

[1] Departamento de Química, Facultad de Ciencias, Universidad de Chile, Santiago

来源：

POLYHEDRON | 1996年 / 15卷 / 17期

关键词：

D O I：

10.1016/0277-5387(95)00571-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of CpFe(dppe)I with thiophenes in the presence of TIPF6 afforded the new complexes [CpFe(dppe)thiophenes]PF6 (thiophenes = thiophene, 2-methyl-thiophene, 3-methyl-thiophene, 2,5-dimethyl-thiophene, benzothiophene and dibenzothiophene). They were characterized by elemental analysis, IR, H-1, P-31 and C-13 NMR as well as by UV-visible spectroscopic methods. Substitution of coordinated thiophenes in [CpFe(dppe)thiophene]PF6 complexes by neutral ligands occurs in mild conditions. (C) 1996 Elsevier Science Ltd.

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收藏

页码：2825 / 2829

页数：5

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