Quantum tunneling of magnetization in lanthanide single-molecule magnets: Bis(phthalocyaninato)terbium and bis(phthalocyaninato)dysprosium anions

被引：553

作者：

Ishikawa, N

Sugita, M

Wernsdorfer, W

机构：

[1] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 11286551, Japan

[2] CNRS, Lab Louis Neel, F-38042 Grenoble, France

[3] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 19期

关键词：

lanthanides; magnetic properties; phthalocyanines; quantum tunneling; single-molecule studies;

D O I：

10.1002/anie.200462638

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Staircase-like structures in the hysteresis loops at 0.04 K (see picture) are shown by doped single crystals of TBA[(Pc) 2Tb0.02111Y0.98111] - (Pc = phthalocyaninato, TBA = tetrabutylammonium), the first lanthanide single-molecule magnet. They are assigned to resonant quantum tunneling of magnetization between entangled states of the electron and nuclear spin systems. The Dy complex was also studied. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2931 / 2935

页数：5

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