Fractal dimension as a tool to guide zeolite synthesis

被引:6
作者
Tatlier, M [1 ]
Erdem-Senatalar, A [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem Engn, TR-80626 Istanbul, Turkey
关键词
D O I
10.1016/S0960-0779(98)00004-6
中图分类号
O1 [数学];
学科分类号
0701 ; 070101 ;
摘要
The borderlines on the composition diagrams between the regions of reaction mixture compositions from which zeolites A, X and HS, as well as amorphous material, may be formed are drawn by using appropriate data from the literature. The fractal dimension is introduced as a helpful tool to depict and quantify the irregular nature of zeolite A synthesis. The random type of behavior, frequently occurring during the synthesis of zeolite A, seems to point to the existence of a factor not yet taken into consideration. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1803 / 1812
页数:10
相关论文
共 13 条
[1]  
[Anonymous], 1992, Chaos and Fractals
[2]   CHEMISTRY IN NONINTEGER DIMENSIONS BETWEEN 2 AND 3 .2. FRACTAL SURFACES OF ADSORBENTS [J].
AVNIR, D ;
FARIN, D ;
PFEIFER, P .
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (07) :3566-3571
[3]   AN EMPIRICAL-MODEL FOR THE NUCLEATION AND GROWTH OF ZEOLITES [J].
BUDD, PM ;
MYATT, GJ ;
PRICE, C ;
CARR, SW .
ZEOLITES, 1994, 14 (03) :198-202
[4]   ZEOLITES AND MOLECULAR-SIEVES - NOT JUST ORDINARY CATALYSTS [J].
DAVIS, ME .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (08) :1675-1683
[5]   First-order kinetics in fractal catalysts: Renormalization analysis of the effectiveness factor. [J].
Giona, M ;
Schwalm, WA ;
Adrover, A ;
Schwalm, MK .
CHEMICAL ENGINEERING SCIENCE, 1996, 51 (10) :2273-2282
[6]  
KOSTINKO JA, 1983, INTRAZEOLITE CHEM
[7]  
Milton R.M., 1959, Molecular Sieve Adsorbents, in, Google Patents, Patent No. [US2882243A, 2882243]
[8]   DETERMINISTIC APPROACHES TO PROBLEMS OF DIFFUSION, REACTION AND ADSORPTION IN A FRACTAL POROUS CATALYST [J].
SHEINTUCH, M ;
BRANDON, S .
CHEMICAL ENGINEERING SCIENCE, 1989, 44 (01) :69-79
[9]   THE FRACTAL DIMENSION IN MOLECULAR-SIEVES - SYNTHETIC FAUJASITE AND RELATED SOLIDS [J].
SULIKOWSKI, B .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (07) :1420-1425
[10]   FRACTAL STRUCTURE OF POROUS SOLIDS CHARACTERIZED BY ADSORPTION [J].
SZE, SJ ;
LEE, TY .
PHYSICAL REVIEW B, 1995, 51 (14) :8709-8714