A dichloropalladium(II) complex with a mixed donor bidentate ligand:: dichloro[2-(diphenylphosphino)-1-(methylthio)ethane-P,S]palladium(II)

被引：11

作者：

Abu-Surrah, AS ^{[1
]}

Lappalainen, K

Klinga, M

Leskelä, M

Hodali, HA

Rieger, B

机构：

[1] Univ Ulm, D-89069 Ulm, Germany

[2] Univ Helsinki, Inorgan Chem Lab, FIN-00014 Helsinki, Finland

[3] Univ Jordan, Fac Sci, Dept Chem, Amman, Jordan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198012773

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [PdCl2(C15H17PS)], was prepared by the reaction of cis-dichlorobis(benzonitrile)palladium(II) with the Ligand 1-(thiomethyl)-2-(diphenylphosphino)ethane in acetone. The crystal structure of the resulting palladium(II) complex has been determined. The length of the Pd-Cl bonds is consistent with the trans-influence order: P > S.

引用

页码：188 / 190

页数：3

共 13 条

[1] Late transition metal complexes: Catalysts for a new generation of organic polymers [J].

AbuSurrah, AS ;

Rieger, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (21) :2475-2477

[2]

ABUSURRAH AS, 1998, J MOL CATAL A-CHEM, V35, P2475

[3]

ABUSURRAH AS, 1990, INORG CHIM ACTA, V174, P223

[4]

ABUSURRAH AS, 1991, TRANSIT METAL CHEM, V16, P458

[5]

ABUSURRAH AS, 1999, UNPUB

[6]

ATWOOD JD, 1997, INORGANIC ORGANOMETA, P48

[7]

Collman J. P., 1980, PRINCIPLES APPL ORGA, P54

[8] COMPLEXES OF SOME MIXED-DONOR LIGANDS WITH RH(I), IR(I) AND IR(III) [J].

KITTANEH, IM ;

HODALI, HA ;

TAYIM, HA .

INORGANICA CHIMICA ACTA-ARTICLES, 1982, 60 (JUN) :223-226

[9]

*MOL STRUCT CORP, 1993, TEXSAN SINGL CRYST S

[10] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

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