Fluorescent aggregates of 1-(p-butyloxyphenyl)-4-(p-cyanophenyl)buta-1E,3E-diene:: Temperature sensing and photoimaging applications

被引:12
作者
Davis, R [1 ]
Das, S [1 ]
机构
[1] CSIR, Reg Res Lab, Div Chem Sci, Trivandrum 695019, Kerala, India
关键词
fluorescence; aggregates; butadienes; sensor; photoimaging;
D O I
10.1007/s10895-005-2983-7
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The use of fluorescent solid films of a 1-(p-butyloxyphenyl)-4-(p-cyanophenyl)buta-1E, 3E-diene as an efficient temperature sensor is described. The fluorescence changes in these films are proposed to occur due to a reversible temperature-dependent variation in its monomer-aggregate ratio. Photoisomerization of the butadiene chromophore in solid films was observed to occur only at elevated temperatures (> 120 degrees C), making the material also useful for reversible photochemical generation of fluorescence patterns with nondestructive readout properties.
引用
收藏
页码:749 / 753
页数:5
相关论文
共 42 条
[1]   Remote thermometry with thermographic phosphors: Instrumentation and applications [J].
Allison, SW ;
Gillies, GT .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (07) :2615-2650
[2]  
Bu''nau G. v., 1970, RANG DALESPHARMACOLO, V74, P1294, DOI [10.1002/bbpc.19700741223, DOI 10.1002/BBPC.19700741223]
[3]   A dual fluorescence temperature sensor based on perylene/exciplex interconversion [J].
Chandrasekharan, N ;
Kelly, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (40) :9898-9899
[4]   Highly efficient organic light-emitting diodes with a silole-based compound [J].
Chen, HY ;
Lam, WY ;
Luo, JD ;
Ho, YL ;
Tang, BZ ;
Zhu, DB ;
Wong, M ;
Kwok, HS .
APPLIED PHYSICS LETTERS, 2002, 81 (04) :574-576
[5]   Aggregation-induced emission of cis,cis-1,2,3,4-tetraphenylbutadiene from restricted intramolecular rotation [J].
Chen, JW ;
Xu, B ;
Ouyang, XY ;
Tang, BZ ;
Cao, Y .
JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (37) :7522-7526
[6]   Characterization of chiral H and J aggregates of cyanine dyes formed by DNA templating using stark and fluorescence spectroscopies [J].
Chowdhury, A ;
Wachsmann-Hogiu, S ;
Bangal, PR ;
Raheem, I ;
Peteanu, LA .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (48) :12196-12201
[7]   Thermally reversible fluorescent polymorphs of alkoxy-cyano-substituted diphenylbutadienes: role of crystal packing in solid state fluorescence [J].
Davis, R ;
Rath, NP ;
Das, S .
CHEMICAL COMMUNICATIONS, 2004, (01) :74-75
[8]   Reversible photochemical phase transition behavior of alkoxy-cyano-substituted diphenylbutadiene liquid crystals [J].
Davis, R ;
Mallia, VA ;
Das, S .
CHEMISTRY OF MATERIALS, 2003, 15 (05) :1057-1063
[9]  
DAVIS R, THESIS U KERALA TRIV
[10]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566