Magnetic properties of tetrakis[4-(α-diazobenzyl)pyridine]bis(thiocyanato-N)cobalt(II) in frozen solution after irradiation.: Formation of a single-molecule magnet in frozen solution

被引：91

作者：

Karasawa, S ^{[1
]}

Zhou, GY ^{[1
]}

Morikawa, H ^{[1
]}

Koga, N ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Pharmaceut Sci, Higashi Ku, Fukuoka 8128582, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 45期

关键词：

D O I：

10.1021/ja035478s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Magnetic properties after irradiation of a 1:4 mixture of Co(SCN)2 and 4-(α-diazobenzyl)pyridine in frozen solution were investigated by ac and dc magneto/susceptometry. Observations of the frequency dependence of X'' signals and of a hysteresis loop at 2 K in ac and dc measurements, respectively, indicate that the generated cobalt?carbene complex functions as a single-molecule magnet. This is the first example of a monometallic single-molecule magnet of nanometer size. Copyright © 2003 American Chemical Society.

引用

页码：13676 / 13677

页数：2

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