Transport properties of electrically conducting nylon 6/foliated graphite nanocomposites

被引:65
作者
Weng, WG [1 ]
Chen, GH [1 ]
Wu, DJ [1 ]
机构
[1] Huaqiao Univ, Coll Mat Sci & Engn, Quanzhou 362021, Peoples R China
基金
中国国家自然科学基金;
关键词
nylon; 6; graphite; nanocomposite;
D O I
10.1016/j.polymer.2005.05.071
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work, we analyze the conductivity data of the nylon 6/FG nanocomposites using the normalized percolation equations and the general effective equation. From the interpretations of the derived results, we demonstrate that the microstructure of the nanocomposites can be readily deduced. Taking several factors into account, it turns out that the tunneling mechanism should be responsible for the observed non-universality of the critical exponents. Experimental evidences show that the existence of the tunneling conduction should be attributed to the particular structure of the prepared materials. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6250 / 6257
页数:8
相关论文
共 33 条
[1]   TUNNELING AND NONUNIVERSAL CONDUCTIVITY IN COMPOSITE-MATERIALS [J].
BALBERG, I .
PHYSICAL REVIEW LETTERS, 1987, 59 (12) :1305-1308
[2]   Electrical conductivity of anisotropic expanded graphite-based monoliths [J].
Celzard, A ;
Marêché, JF ;
Furdin, G ;
Puricelli, S .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2000, 33 (23) :3094-3101
[3]   Non-universal conductivity critical exponents in anisotropic percolating media:: a new interpretation [J].
Celzard, A ;
Marêché, JF .
PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2003, 317 (3-4) :305-312
[4]   Electrical conductivity of carbonaceous powders [J].
Celzard, A ;
Marêché, JF ;
Payot, F ;
Furdin, G .
CARBON, 2002, 40 (15) :2801-2815
[5]   Measurements of universal and non-universal percolation exponents in macroscopically similar systems [J].
Chiteme, C ;
McLachlan, DS .
PHYSICA B-CONDENSED MATTER, 2000, 279 (1-3) :69-71
[6]   EXFOLIATION OF GRAPHITE [J].
CHUNG, DDL .
JOURNAL OF MATERIALS SCIENCE, 1987, 22 (12) :4190-4198
[7]  
DECHKOVSKAYA K, 1953, RUBBER CHEM TECHNOL, V26, P810
[8]   THE MEASUREMENT AND COMPARATIVE-ANALYSIS OF THE ELECTRICAL AND THERMAL-CONDUCTIVITIES, PERMEABILITY AND YOUNGS MODULUS OF SINTERED NICKEL [J].
DEPREZ, N ;
MCLACHLAN, DS ;
SIGALAS, I .
SOLID STATE COMMUNICATIONS, 1988, 66 (08) :869-872
[9]   THE ANALYSIS OF THE ELECTRICAL-CONDUCTIVITY OF GRAPHITE POWDERS DURING COMPACTION [J].
DEPREZ, N ;
MCLACHLAN, DS .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1988, 21 (01) :101-107
[10]   CHARGE TRANSPORT IN POLYETHYLENE GRAPHITE COMPOSITE-MATERIALS [J].
EZQUERRA, TA ;
KULESCZA, M ;
CRUZ, CS ;
BALTACALLEJA, FJ .
ADVANCED MATERIALS, 1990, 2 (12) :597-600