Crystallization behavior and morphology of biodegradable polylactide/layered silicate nanocomposite

被引:374
作者
Nam, JY [1 ]
Ray, SS [1 ]
Okamoto, M [1 ]
机构
[1] Toyota Technol Inst, Grad Sch Engn, Adv Polymers Mat Engn, Nagoya, Aichi 4688511, Japan
关键词
D O I
10.1021/ma034623j
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
An intercalated polylactide (PLA)/layered silicate nanocomposite was prepared by simple melt extrusion of PLA and organically modified montmorillonite. The detailed crystallization kinetics and morphology of neat PLA before and after nanocomposite preparation were studied by using polarized optical microscopy, light scattering, differential scanning calorimetric, and wide-angle X-ray diffraction analyses. The overall crystallization rate and spherulitic texture of pure PLA were strongly influenced in the presence of montmorillonite particles.
引用
收藏
页码:7126 / 7131
页数:6
相关论文
共 45 条
[1]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[2]  
Biswas M, 2001, ADV POLYM SCI, V155, P167
[3]   Mechanism of the stereocomplex formation between enantiomeric poly(lactide)s [J].
Brizzolara, D ;
Cantow, HJ ;
Diederichs, K ;
Keller, E ;
Domb, AJ .
MACROMOLECULES, 1996, 29 (01) :191-197
[4]  
Drumright RE, 2000, ADV MATER, V12, P1841, DOI 10.1002/1521-4095(200012)12:23<1841::AID-ADMA1841>3.3.CO
[5]  
2-5
[6]   BIODEGRADABLE MATERIALS OF POLY(L-LACTIC ACID) .1. MELT-SPUN AND SOLUTION-SPUN FIBERS [J].
ELING, B ;
GOGOLEWSKI, S ;
PENNINGS, AJ .
POLYMER, 1982, 23 (11) :1587-1593
[7]   INVESTIGATION OF STRUCTURE OF SOLUTION GROWN CRYSTALS OF LACTIDE COPOLYMERS BY MEANS OF CHEMICAL-REACTIONS [J].
FISCHER, EW ;
STERZEL, HJ ;
WEGNER, G .
KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE, 1973, 251 (11) :980-990
[8]   Well-controlled biodegradable nanocomposite foams: From microcellular to nanocellular [J].
Fujimoto, Y ;
Ray, SS ;
Okamoto, M ;
Ogami, A ;
Yamada, K ;
Ueda, K .
MACROMOLECULAR RAPID COMMUNICATIONS, 2003, 24 (07) :457-461
[9]  
Giannelis EP, 1999, ADV POLYM SCI, V138, P107
[10]   Polymer layered silicate nanocomposites [J].
Giannelis, EP .
ADVANCED MATERIALS, 1996, 8 (01) :29-&