A study of transferability of atomic background on EXAFS spectra of simple gaseous compounds of As

被引:8
作者
Kodre, A
Preseren, R
Arcon, I
Gomilsek, JP
Borowski, M
机构
[1] Fac Math & Phys, SI-1000 Ljubljana, Slovenia
[2] Jozef Stefan Inst, SI-1001 Ljubljana, Slovenia
[3] Nova Gorica Polytech, SI-5000 Nova Gorica, Slovenia
[4] Fac Mech Engn, SI-2000 Maribor, Slovenia
[5] European Synchrotron Radiat Facil, F-38043 Grenoble, France
关键词
atomic background transferability; AsK-edge EXAFS; As; As2O3 and AsH3 gases;
D O I
10.1107/S0909049500015363
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
From EXAFS spectra of As and As2O3 vapors and arsine gas AsH3 the ab initio calculated structural signal is removed. The remainders comprise small absorption edges due to shake-up channels involving electrons from 3d or 3p subshell. With enhanced resolution, the edges reveal a fine splitting and a varying contribution of resonance channels, due to individual molecular energy-level structure of the samples. On the resolution level appropriate for routine EXAFS analysis the remainders coincide, representing a unique and transferable atomic absorption background for the range of As valence states spanned by the samples.
引用
收藏
页码:282 / 284
页数:3
相关论文
共 32 条
[1]  
ARCON I, 1997, J PHYS IV S, V7, P223
[2]   AN ITERATIVE APPROACH TO ATOMIC BACKGROUND REMOVAL IN XAFS DATA-ANALYSIS [J].
BRIDGES, F ;
BOOTH, CH ;
LI, GG .
PHYSICA B, 1995, 208 (1-4) :121-124
[3]   INFLUENCE OF DOUBLE-ELECTRON TRANSITIONS ON THE EXAFS L EDGES OF RARE-EARTH SYSTEMS [J].
CHABOY, J ;
MARCELLI, A ;
TYSON, TA .
PHYSICAL REVIEW B, 1994, 49 (17) :11652-11661
[4]  
Cyvin S. J., 1968, MOL VIBRATIONS MEAN
[5]   Evidence for multielectron resonances at the Sr K edge [J].
DAngelo, P ;
Nolting, HF ;
Pavel, NV .
PHYSICAL REVIEW A, 1996, 53 (02) :798-805
[6]   DOUBLE-ELECTRON EXCITATION CHANNELS AT THE BR K-EDGE OF HBR AND BR2 [J].
DANGELO, P ;
DICICCO, A ;
FILIPPONI, A ;
PAVEL, NV .
PHYSICAL REVIEW A, 1993, 47 (03) :2055-2063
[7]   EXAFS STUDY OF MICELLAR AGGREGATES OF BILE-ACID RUBIDIUM SALTS [J].
DANGELO, P ;
DINOLA, A ;
GIGLIO, E ;
MANGONI, M ;
PAVEL, NV .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (15) :5471-5480
[8]   High-pressure EXAFS measurements of solid and liquid Kr [J].
DiCicco, A ;
Filipponi, A ;
Itie, JP ;
Polian, A .
PHYSICAL REVIEW B, 1996, 54 (13) :9086-9098
[9]   EXAFS MULTIPLE-SCATTERING DATA-ANALYSIS - GNXAS METHODOLOGY AND APPLICATIONS [J].
DICICCO, A .
PHYSICA B, 1995, 208 (1-4) :125-128
[10]  
DICICCO A, 1995, PHYSICA B, V209, P125