Silyloxy-cope rearrangement of chiral aldol adducts

被引:26
作者
Black, WC
Giroux, A
Greidanus, G
机构
[1] Merck Frosst Ctr. for Therapeut. R., Pointe-Claire-Dorval, Que. H9R 4P8
关键词
D O I
10.1016/0040-4039(96)00904-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The silyloxy-Cope rearrangement of a chiral 1,5-diene generated from aldol condensation proceeds in high yield and selectivity under mild thermal conditions to generate a new stereocenter five atoms removed from the chiral auxiliary. Copyright (C) 1996 Elsevier Science Ltd
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页码:4471 / 4474
页数:4
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