Hydrothermal synthesis of polymeric metal carboxylates from benzene-1,2,4,5-tetracarboxylic acid and benzene-1,2,4-tricarboxylic acid

被引：90

作者：

Plater, MJ

Foreman, MRS

Howie, RA

Skakle, JMS

Slawin, AMZ

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

[2] Univ St Andrews, Mol Struct Lab, St Andrews KY16 9ST, Fife, Scotland

来源：

INORGANICA CHIMICA ACTA | 2001年 / 315卷 / 01期

关键词：

hydrothermal; coordination polymers; CRystal engineering;

D O I：

10.1016/S0020-1693(01)00318-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystallisation of benzene-1,2,4,5-tetracarboxylic acid or benzene-1,2,4-tricarboxylic acid with divalent metal-ions Co, Mn or Zn and 2,2-bipyridyl gives coordination solids of composition [Co-2(C10H2O8)(C10H8N2)(2)(H2O)] (1), [Co-3(C9H3O6)(2)(C10H8N2)(2)-(H2O)(2)] (2), [Mn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (3) or [Zn-3(C9H3O6)(2)(C10H8N2)(2)(H2O)(2)] (4). Each has a sheet structure with a distorted octahedral coordination environment. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：126 / 132

页数：7

共 9 条

[1]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[2]

*BRUK, 1999, SMART SAINT SADABS S

[3] Zeolite-like crystal structure of an empty microporous molecular framework [J].