Complexes of metal(II) halides of the first transition series with N,N,N′,N′-tetramethylmethane-diamine, -ethane-1,2-diamine and -propane-1,3-diamine

被引：38

作者：

Handley, DA ^{[1
]}

Hitchcock, PB ^{[1
]}

Lee, TH ^{[1
]}

Leigh, GJ ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANICA CHIMICA ACTA | 2001年 / 314卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

metal(II) halides; first transition series; dinuclear species; mononuclear species; x-ray crystal structures;

D O I：

10.1016/S0020-1693(00)00384-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of metal(IT) halides of the first transition series with three diamines Me2N(CH2)(n)NMe2 have been studied. For n = 1 (tmmn), only dinuclear species [{MX2(tmmn)}(2)] have been isolated, whereas for n = 3 (tmpn) only tetrahedral mononuclear species [MX2(tmpn)] have been characterised. For n = 2 (tmen), structures of both kinds have been prepared. and also of a third kind, octahedral trans-[MX2(tmen)(2)]. These different structures are often interconvertible. The structural types are rationalised in terms of the dimensions of the diamines rather than of the properties of the metal(II) ions. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：14 / 21

页数：8

共 10 条

[1] Synthesis, structure, and magnetic properties of [CrCl(-mu Cl)(TMEDA)](2) [J].

Bachmann, B ;

Heck, J ;

Hahn, F ;

Massa, W ;

Pebler, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (12) :2061-2064

[2] Mono-, di-, and tri-nuclear complexes of iron(II) with N,N,N',N'-tetramethylethylenediamine [J].

Davies, SC ;

Hughes, DL ;

Leigh, GJ ;

Sanders, JR ;

deSouza, JS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (11) :1981-1988

[3] NOVEL TITANIUM(II) AMINE COMPLEXES L4TICL2[L = 1/2 N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE (TMEDA), 1/2 N,N,N'-TRIMETHYLETHYLENEDIAMINE, PYRIDINE, 1/2 2,2'-BIPYRIDINE] - SYNTHESIS AND CRYSTAL-STRUCTURE OF MONOMERIC TRANS-(TMEDA)2TICL2 [J].

EDEMA, JJH ;

DUCHATEAU, R ;

GAMBAROTTA, S ;

HYNES, R ;

GABE, E .

INORGANIC CHEMISTRY, 1991, 30 (02) :154-156

[4] NOVEL VANADIUM(II) AMINE COMPLEXES - A FACILE ENTRY IN THE CHEMISTRY OF DIVALENT VANADIUM - SYNTHESIS AND CHARACTERIZATION OF MONONUCLEAR L4VCL2 [L = AMINE, PYRIDINE] - X-RAY STRUCTURES OF TRANS-(TMEDA)2VCL2 [TMEDA = N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE] AND TRANS-MZ2V(PY)2 [MZ = O-C6H4CH2N(CH3)2, PY = PYRIDINE] [J].

EDEMA, JJH ;

STAUTHAMER, W ;

VANBOLHUIS, F ;

GAMBAROTTA, S ;

SMEETS, WJJ ;

SPEK, AL .

INORGANIC CHEMISTRY, 1990, 29 (07) :1302-1306

[5] MOLECULAR-STRUCTURE OF BIS[DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINECOPPER(II)],[CU(TMEN)CL2]2 [J].

ESTES, ED ;

ESTES, WE ;

HATFIELD, WE ;

HODGSON, DJ .

INORGANIC CHEMISTRY, 1975, 14 (01) :106-109

[6] Triangulo-pentahalotrimetal complexes of nickel(II) and cobalt(II) with N,N,N′,N′,N-tetrametbylethane-1,2-diamine and related compounds [J].

Handley, DA ;

Hitchcock, PB ;

Leigh, GJ .

INORGANICA CHIMICA ACTA, 2001, 314 (1-2) :1-13

[7]

HANDLEY DA, UNPUB

[8] New compounds containing the triangulo-trichlorotrivanadium(II) moiety [J].

Hitchcock, PB ;

Hughes, DL ;

Larkworthy, LF ;

Leigh, GJ ;

Marmion, CJ ;

Sanders, JR ;

Smith, GW ;

deSouza, JS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (07) :1127-1135

[9]

LUUKKONEN A, 1973, LANGES HDB CHEM, V46, P392

[10] Polynuclear aggregation of cobalt and manganese dichlorides. Synthesis, properties and structures of monomeric [CoCl2(tmen)], ionic [CO3(mu(3)-Cl)(2)-(mu-Cl)(3)(tmen)(3)][BPh(4)], polymeric MnCl2 center dot tmen and tetranuclear [Mn-4-(mu-Cl)(6)Cl-2(tmen)(4)] (tmen=Me(2)NCH(2)CH(2)NMe(2)) [J].

Sobota, P ;

Utko, J ;

Szafert, S ;

Janas, Z ;

Glowiak, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (16) :3469-3473

← 1 →