Rhodium-catalyzed addition of phenylmethyldifluorosilane to aldehydes

被引：60

作者：

Oi, S ^{[1
]}

Moro, M ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Chem Mat, Sendai, Miyagi 9808579, Japan

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 06期

关键词：

D O I：

10.1021/om0009684

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Phenylmethyldifluorosilane reacts with aldehydes in the presence of a fluoride salt and a catalytic amount of a cationic rhodium complex, [Rh(cod)(CH3CN)(2)]BF4, affording the corresponding phenylated alcohols in good yield. The reaction mechanism involves the transmetalation between a fluorine-coordinated silicate and a rhodium complex to generate a phenylrhodium species.

引用

页码：1036 / 1037

页数：2

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