Thin films of copper hexadecafluorophthalocyanine CuPcF16

被引:27
作者
Basova, T
Kol'tsov, E
Hassan, A
Tsargorodskaya, A
Ray, A
Igumenov, I
机构
[1] VI Nikitin Chem Inst, Novosibirsk 630090, Russia
[2] Sheffield Hallam Univ, Sch Engn, Nanotechnol Res Lab, Sheffield S1 1WB, S Yorkshire, England
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2005年 / 242卷 / 04期
关键词
D O I
10.1002/pssb.200460009
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In this work, structural features and optical properties of CuPcF16 films deposited by physical vapour deposition have been investigated. Thin films of two different thicknesses (22 and 198 nm) were characterized by ellipsometry, optical absorption spectroscopy and scanning electron microscopy. Film morphology and optical properties are found to depend on film thickness. Absorption spectra of CuPcF16, films were compared with those of unsubstituted copper phthalocyanine. The sensor response of CuPcF16 film to ammonia was studied using surface plasmon resonance measurements. It was stated that strong electron-withdrawing fluorine substituents make this compound sensitive to reducing gases such as NH3 while unsubstituted CuPc is practically insensitive to this gas.
引用
收藏
页码:822 / 827
页数:6
相关论文
共 13 条
[1]   New air-stable n-channel organic thin film transistors [J].
Bao, ZA ;
Lovinger, AJ ;
Brown, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (01) :207-208
[2]  
DAVYDOV AS, 1968, THEORY MOL EXITONS, pCH5
[3]   SPECTRAL AND ELECTROCHEMICAL PROPERTIES OF VANADYL HEXADECAFLUOROPHTHALOCYANINE [J].
HANDA, M ;
SUZUKI, A ;
SHOJI, S ;
KASUGA, K ;
SOGABE, K .
INORGANICA CHIMICA ACTA, 1995, 230 (1-2) :41-44
[4]   Spectroelectrochemical investigations on the reduction of thin films of hexadecafluorophthalocyaninatozinc (F16PcZn) [J].
Hesse, K ;
Schlettwein, D .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 476 (02) :148-158
[5]   Influence of surface reactions and ionization gradients on junction properties of F16PcZn [J].
Hiller, S ;
Schlettwein, D ;
Armstrong, NR ;
Wohrle, D .
JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (04) :945-954
[6]  
Kasha M., 1965, Pure Appl. Chem, V11, P371, DOI [10.1351/pac196511030371, DOI 10.1351/PAC196511030371]
[7]   Synthesis and investigations of copper hexadecafluorophthalocyanine CuPcF16 [J].
Kol'tsov, E ;
Basova, T ;
Semyannikov, P ;
Igumenov, I .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 86 (01) :222-227
[8]  
Leznoff C.C., 1989, PHTHALOCYANINES PROP
[9]   Study of adsorption of some organic molecules in calix[4]resorcinolarene LB films by surface plasmon resonance [J].
Nabok, AV ;
Hassan, AK ;
Ray, AK ;
Omar, O ;
Kalchenko, VI .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 45 (02) :115-121
[10]  
Schlettwein D, 2000, LANGMUIR, V16, P2872, DOI 10.1021/1a99111i