Ruthenium-catalyzed addition of aromatic imines at the ortho C-H bonds to olefins

被引：129

作者：

Kakiuchi, F ^{[1
]}

Yamauchi, M ^{[1
]}

Chatani, N ^{[1
]}

Murai, S ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 02期

关键词：

D O I：

10.1246/cl.1996.111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Additions of aromatic imines at the ortho carbon-hydrogen bonds to olefins were catalyzed by ruthenium complexes affording 1:1 addition products in good to excellent yields, In some cases, a by-product arising from dehydrogenative coupling was also obtained, Both aldimines and ketimines reacted well. Olefins such as styrene, 3,3-dimethyl-1-butene, and ethylene yielded corresponding products in good yields.

引用

页码：111 / 112

页数：2

共 17 条

[1] CYCLOMETALATED PLATINUM(II) COMPOUNDS WITH FLUORINATED IMINIC LIGANDS - SYNTHESIS AND REACTIVITY TUNING - CRYSTAL-STRUCTURES OF THE COMPOUNDS [PTME(RCH=NCH2C6H5)(PPH3)] (R=2,3,4-C6HF3 AND 2,3-C6H2F2)
CRESPO, M
SOLANS, X
FONTBARDIA, M
[J]. ORGANOMETALLICS, 1995, 14 (01) : 355 - 364
[2] MONOAZADIENES RUTHENIUM CARBONYL CHEMISTRY
ELSEVIER, CJ
MUL, WP
VRIEZE, K
[J]. INORGANICA CHIMICA ACTA, 1992, 198 : 689 - 703
[3] RUTHENIUM-CATALYZED CHEMICAL MODIFICATION OF UNSATURATED POLYMERS
GUO, HJ
TAPSAK, MA
WEBER, WP
[J]. POLYMER BULLETIN, 1994, 33 (04) : 417 - 423
[4] RUTHENIUM-CATALYZED REGIOSELECTIVE COPOLYMERIZATION OF ACETOPHENONE AND ALPHA,OMEGA-DIENES - ADDITION OF AROMATIC ORTHO C-H BONDS ACROSS C-C DOUBLE-BONDS OF ALPHA,OMEGA-DIENES
GUO, HJ
WEBER, WP
[J]. POLYMER BULLETIN, 1994, 32 (5-6) : 525 - 528
[5] CATALYTIC ADDITION OF OLEFINIC C-H BONDS TO OLEFINS
KAKIUCHI, F
TANAKA, Y
SATO, T
CHATANI, N
MURAI, S
[J]. CHEMISTRY LETTERS, 1995, (08) : 679 - 680
[6] CATALYTIC ADDITION OF AROMATIC C-H BONDS TO ACETYLENES
KAKIUCHI, F
YAMAMOTO, Y
CHATANI, N
MURAI, S
[J]. CHEMISTRY LETTERS, 1995, (08) : 681 - 682
[7] CATALYTIC ADDITION OF AROMATIC CARBON-HYDROGEN BONDS TO OLEFINS WITH THE AID OF RUTHENIUM COMPLEXES
KAKIUCHI, F
SEKINE, S
TANAKA, Y
KAMATANI, A
SONODA, M
CHATANI, N
MURAI, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (01) : 62 - 83
[8] ACTIVATION OF CARBON FLUORINE BONDS BY METAL-COMPLEXES
KIPLINGER, JL
RICHMOND, TG
OSTERBERG, CE
[J]. CHEMICAL REVIEWS, 1994, 94 (02) : 373 - 431
[9] RHODIUM-CATALYZED REGIOSELECTIVE ALKYLATION OF THE PHENYL RING OF 2-PHENYLPYRIDINES WITH OLEFINS
LIM, YG
KIM, YH
KANG, JB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (19) : 2267 - 2268
[10] McCarty CG., 1970, Carbon-Nitrogen Double Bonds, P363, DOI 10.1002/9780470771204.ch9

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