A new design strategy for organic optoelectronic materials by lateral boryl substitution

被引:216
作者
Elbing, Mark [1 ,2 ,3 ]
Bazan, Guillermo C. [1 ,2 ,3 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Biochem, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Mat Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
关键词
boron; conjugation; fluorescence; molecular design; organic electronics;
D O I
10.1002/anie.200703722
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Lateral thinking: Molecular solids with tunable color and excellent emission efficiencies or increased electron affinities have been obtained by lateral boryl substitution on a π-delocalized framework (see picture, D = donor group, B = boryl group). This approach gives rise to a new design principle for organic optoelectronic materials. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:834 / 838
页数:5
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