Organometallic nanoparticles of metals or metal oxides

被引:36
作者
Chaudret, B. [1 ]
Philippot, K. [1 ]
机构
[1] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse, France
来源
OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES | 2007年 / 62卷 / 06期
关键词
D O I
10.2516/ogst:2007062
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Organometallic Nanoparticles of Metals or Metal Oxides - This paper presents an overview of the results obtained in the synthesis of metal or metal oxide nanoparticles using hydrocarbyl complexes as metal source. The main advantage of using such metal precursors is their easy decomposition that can be achieved in solution and mild conditions. This allows the control of the particles size, shape and surface state in order to reach a monodisperse assembly of particles having the desired property. The results are reported taking into account the nature of the metal as well as in some cases the stabilizing mode (polymers, ligands, ionic liquids). Some results obtained in the deposition of metal nanoparticles within the channels of templates such as alumina membranes and mesoporous silica through a classsical impregnation method are also reported. The last part concerns the preparation of metal nanoparticles supported on a porous support using a fluidized bed.
引用
收藏
页码:799 / 817
页数:19
相关论文
共 115 条
[1]   MAGNETISM FROM THE ATOM TO THE BULK IN IRON, COBALT, AND NICKEL CLUSTERS [J].
BILLAS, IML ;
CHATELAIN, A ;
DEHEER, WA .
SCIENCE, 1994, 265 (5179) :1682-1684
[2]   Nanoscale colloidal metals and alloys stabilized by solvents and surfactants - Preparation and use as catalyst precursors [J].
Bonnemann, H ;
Braun, G ;
Brijoux, W ;
Brinkmann, R ;
Tilling, AS ;
Seevogel, K ;
Siepen, K .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :143-162
[3]   Enantioselective hydrogenations on platinum colloids [J].
Bonnemann, H ;
Braun, GA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (17) :1992-1995
[4]   PREPARATION AND CHARACTERIZATION OF ORGANOSOLS OF MONODISPERSED NANOSCALE PALLADIUM - PARTICLE-SIZE EFFECTS IN THE BINDING GEOMETRY OF ADSORBED CARBON-MONOXIDE [J].
BRADLEY, JS ;
HILL, EW ;
BEHAL, S ;
KLEIN, C ;
CHAUDRET, B ;
DUTEIL, A .
CHEMISTRY OF MATERIALS, 1992, 4 (06) :1234-1239
[5]   The role of Pd nanoparticles in ionic liquid in the Heck reaction [J].
Cassol, CC ;
Umpierre, AP ;
Machado, G ;
Wolke, SI ;
Dupont, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3298-3299
[6]   SYNTHESIS OF PALLADIUM AND PLATINUM NANOCLUSTERS WITHIN MICROPHASE-SEPARATED DIBLOCK COPOLYMERS [J].
CHAN, YNC ;
CRAIG, GSW ;
SCHROCK, RR ;
COHEN, RE .
CHEMISTRY OF MATERIALS, 1992, 4 (04) :885-894
[7]   Organometallic approach to nanoparticles synthesis and self-organization [J].
Chaudret, B .
COMPTES RENDUS PHYSIQUE, 2005, 6 (01) :117-131
[8]   Chemisorption on nickel nanoparticles of various shapes: Influence on magnetism [J].
Cordente, N ;
Amiens, C ;
Chaudret, B ;
Respaud, M ;
Senocq, F ;
Casanove, MJ .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (10) :6358-6365
[9]   Synthesis and magnetic properties of nickel nanorods [J].
Cordente, N ;
Respaud, M ;
Senocq, F ;
Casanove, MJ ;
Amiens, C ;
Chaudret, B .
NANO LETTERS, 2001, 1 (10) :565-568
[10]   Recent advances in the liquid-phase syntheses of inorganic nanoparticles [J].
Cushing, BL ;
Kolesnichenko, VL ;
O'Connor, CJ .
CHEMICAL REVIEWS, 2004, 104 (09) :3893-3946