Catalytic polyaniline-supported electrodes for application in electrocatalysis

被引：32

作者：

Kessler, T

Luna, AMC

机构：

[1] Natl Univ La Plata, Fac Ciencias Exactas, Inst Invest Fisicoquim Teor & Aplicadas, RA-1900 La Plata, Argentina

[2] Univ Nacl Ctr Prov Buenos Aires, Fac Ingn, RA-7400 Olavarria, Argentina

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2003年 / 7卷 / 09期

关键词：

carbon monoxide; methanol; platinum; polyaniline; ruthenium;

D O I：

10.1007/s10008-003-0360-5

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Polyaniline (Pani) films prepared on Au wires were employed as substrates to deposit Pt, Pt-Ru, Pt-Os, Pt-Mo and Pt-Ru-Os or Pt-Ru-Mo by using appropriate working solutions and a potential-programmed perturbation. The atomic percentages of the different metals on Pani were determined by EDAX and their particle size and distribution by SEM. The catalytic activity was tested for adsorbed CO and CH3OH electrooxidation. Accordingly, the best binary and ternary metal combination resulted in Pt-Ru and Pt-Ru-Os.

引用

页码：593 / 598

页数：6

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