Impact of Biomass-Derived contaminants on SOFCs with Ni/Gadolinia-doped ceria anodes

被引:66
作者
Aravind, P. V. [1 ]
Ouweltjes, J. P. [2 ]
Woudstra, N. [1 ]
Rietveld, G. [2 ]
机构
[1] Delft Univ Technol, Sect Energy Technol, NL-2628 CA Delft, Netherlands
[2] Energy Res Ctr Netherlands ECN, NL-1755 ZG Petten, Netherlands
关键词
D O I
10.1149/1.2820452
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The impact of biomass-derived contaminants on solid-oxide fuel cells (SOFCs) with Ni/gadolinia-doped ceria (GDC) anodes was investigated using electrochemical impedance analysis. Measurements were carried out with symmetric test cells under a single-gas atmosphere. The impact of H2S, HCl, and naphthalene in the gas stream on the performance of Ni/GDC anodes are presented. No significant impact has been observed up to 9 ppm H2S and HCl and 110 ppm naphthalene. (c) 2007 The Electrochemical Society.
引用
收藏
页码:B24 / B28
页数:5
相关论文
共 18 条
[1]  
Aravind P.V., 2007, THESIS DELFT U TECHN
[2]  
ARAVIND PV, 2005, SOLID OXIDE FUEL CEL, P1459
[3]   The impact of wood-derived gasification gases on Ni-CGO anodes in intermediate temperature solid oxide fuel cells [J].
Baron, S ;
Brandon, N ;
Atkinson, A ;
Steele, B ;
Rudkin, R .
JOURNAL OF POWER SOURCES, 2004, 126 (1-2) :58-66
[4]   Gas concentration impedance of solid oxide fuel cell anodes I. Stagnation point flow geometry [J].
Bessler, Wolfgang G. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (08) :A1492-A1504
[5]  
Dayton D, 2002, Review of the Literature on Catalytic Biomass Tar Destruction: Milestone Completion Report
[6]  
Dekker NJJ, 2004, 6 EUR SOL OX FUEL CE, P1524
[7]   Transition metal oxides for hot gas desulphurisation [J].
Elseviers, WF ;
Verelst, H .
FUEL, 1999, 78 (05) :601-612
[8]  
Krishnan GN, 1996, HIGH TEMPERATURE GAS, P405
[9]  
KURKELA E, 1996, GASIFICATION DANISH, V291
[10]   The poisoning effect of sulfur-containing impurity gas on a SOFC anode: Part I. Dependence on temperature, time, and impurity concentration [J].
Matsuzaki, Y ;
Yasuda, I .
SOLID STATE IONICS, 2000, 132 (3-4) :261-269