Acceleration of the through space S1 energy transfer rates in cofacial bisporphyrin bio-inspired models by virtue of substituents effect on the Forster J integral and its implication in the antenna effect in the photosystems

被引：25

作者：

Camus, Jean-Michel ^{[1
]}

Aly, Shawkat M. ^{[2
]}

Stern, Christine ^{[1
]}

Guilard, Roger ^{[1
]}

Harvey, Pierre D. ^{[1
,2
]}

机构：

[1] Univ Bourgogne, Inst Chim Mol, ICMUB, UMR 5260, Dijon, France

[2] Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 31期

基金：

加拿大自然科学与工程研究理事会;

关键词：

DIPORPHYRINS; PORPHYRINS;

D O I：

10.1039/c1cc12839f

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The singlet k(ET) for cofacial beta-octaalkylporphyrin/bis(meso-aryl)-porphyrin dyads increases linearly with the gap between the donor-acceptor 0-0 fluorescence peaks at 77 K.

引用

页码：8817 / 8819

页数：3

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