Baeyer-Villiger oxidations with a difference: molecular sieve redox catalysts for the low-temperature conversion of ketones to lactones

被引：68

作者：

Raja, R ^{[1
]}

Thomas, JM ^{[1
]}

Sankar, G ^{[1
]}

机构：

[1] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1X 4BS, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 06期

关键词：

D O I：

10.1039/a900080a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Redox molecular sieve catalysts MAIPO-36 (M = Mn or Co) convert cyclopentanone, cyclohexanone, 2-methylcyclohexanone and adamantan-2-one to their corresponding lactones with high efficiency (selectivities in excess of 90%, conversions in the range 50 to 85%), in the presence of O-2 and PhCHO as sacrificial oxidant.

引用

页码：525 / 526

页数：2

共 14 条

[1] X-ray absorption spectroscopic study of Bronsted, Lewis, and redox centers in cobalt-substituted aluminum phosphate catalysts [J].

Barrett, PA ;

Sankar, G ;

Catlow, CRA ;

Thomas, JM .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (21) :8977-8985

[2]

CRIEGEE R, 1948, LIEBIGS ANN CHEM, V560, P127

[3] OXIDATION OF ORGANIC SUBSTRATES BY MOLECULAR-OXYGEN ALDEHYDE HETEROPOLYOXOMETALATE SYSTEM [J].

HAMAMOTO, M ;

NAKAYAMA, K ;

NISHIYAMA, Y ;

ISHII, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (23) :6421-6425

[4] SIMPLE AND EFFICIENT SYNTHESIS OF METHYLTRIOXORHENIUM (VII) - A GENERAL-METHOD [J].

HERRMANN, WA ;

KUHN, FE ;

FISCHER, RW ;

THIEL, WR ;

ROMAO, CC .

INORGANIC CHEMISTRY, 1992, 31 (21) :4431-4432

[5] HETEROGENEOUS BAEYER-VILLIGER OXIDATION OF KETONES USING AN OXIDANT CONSISTING OF MOLECULAR-OXYGEN AND ALDEHYDES IN THE PRESENCE OF HYDROTALCITE CATALYSTS [J].

KANEDA, K ;

UENO, S ;

IMANAKA, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :797-798

[6] A manganese-containing molecular sieve catalyst designed for the terminal oxidation of dodecane in air [J].

Raja, R ;

Thomas, JM .

CHEMICAL COMMUNICATIONS, 1998, (17) :1841-1842

[7] Cobalt-catalyzed partial oxidation of olefins and ethers using molecular oxygen [J].

Reetz, MT ;

Tollner, K .

TETRAHEDRON LETTERS, 1995, 36 (52) :9461-9464

[8] Redox solid catalysts for the selective oxidation of cyclohexane in air [J].

Sankar, G ;

Raja, R ;

Thomas, JM .

CATALYSIS LETTERS, 1998, 55 (01) :15-23

[9]

Strukul G, 1998, ANGEW CHEM INT EDIT, V37, P1199, DOI 10.1002/(SICI)1521-3773(19980518)37:9<1198::AID-ANIE1198>3.0.CO

[10]

2-Y

← 1 2 →