Atom-transfer within the coordination sphere of early-late heterobimetallic complexes:: rapid deoxygenation of sulfoxides at low temperatures

被引：30

作者：

Fabre, S

Findeis, B

Trösch, DJM

Gade, LH

Scowen, IJ

McPartlin, M

机构：

[1] Univ Strasbourg 1, Inst Le Bel, Lab Chim Organomet & Catalyse, F-67070 Strasbourg, France

[2] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[3] Univ N London, Sch Appl Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 07期

关键词：

D O I：

10.1039/a900010k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extremely rapid oxygen transfer from sulfoxides to a carbonyl ligand to give the corresponding thioether and coordinated CO2 is observed in the reactions of unsupported Zr-Ru heterodimetallic complexes with sulfoxides; this is interpreted to arise from the cooperative reactivity of the two complementary metal complex fragments bound to each other through a highly polar metal-metal bond.

引用

收藏

页码：577 / 578

页数：2

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