Reaction of [Bu4N]2[Pd2Br6(Se2N2)] with [14]aneS4;: an effective source of the diselenium dinitride unit

被引：2

作者：

Aucott, Stephen M.

Drennan, Dennis

James, Sarah L. M.

Kelly, Paul F. ^{[1
]}

Slawin, Alexandra M. Z.

机构：

[1] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 29期

关键词：

D O I：

10.1039/b707450f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Bu4N](2)[ Pd2Br6(Se2N2)] with [14]aneS(4) results in eventual formation of Se4N4; intermediates in this reaction include an air-sensitive insoluble material which reacts with [PtCl2(PMe2Ph)](2) to give the first example of a platinum adduct of Se2N2 and with [ Pd2Br6](2-) to regenerate the starting material.

引用

收藏

页码：3054 / 3056

页数：3

相关论文

共 12 条

[1] Bis(tetra-n-butylammonium) (μ-N,N′-diselenium dinitride)bis[tribromopalladate(II)] [J].

Aucott, SM ;

Dale, SH ;

Elsegood, MRJ ;

Holmes, KE ;

James, SLM ;

Kelly, PF .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 :M643-M644

[2]

Banister AJ, 1998, ADV MATER, V10, P1415, DOI 10.1002/(SICI)1521-4095(199812)10:17<1415::AID-ADMA1415>3.0.CO

[3]

2-L

[4]

Chivers T, 2005, GUIDE TO CHALCOGEN-NITROGEN CHEMISTRY, P1, DOI 10.1142/9789812563118

[5] FACILE INTRODUCTION OF N-15 INTO CHALCOGEN NITROGEN SYSTEMS USING N-15-LABELED AMMONIA [J].

GINN, VC ;

KELLY, PF ;

WOOLLINS, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (13) :2129-2130

[6] Use of Se4N4 and Se(NSO)(2) in the preparation of palladium adducts of diselenium dinitride, Se2N2; Crystal structure of [PPh(4)](2)[Pd2Br6(Se2N2)] [J].

Kelly, PF ;

Slawin, AMZ ;

SorianoRama, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (04) :559-562

[7] Preparation and crystal structure of [(AlBr3)(2)(Se2N2)], the first example of a main-group element adduct of diselenium dinitride [J].

Kelly, PF ;

Slawin, AMZ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (21) :4029-4030

[8] THE PREPARATION OF SALTS OF [PD-2(MU-SE2N2)CL-6](2-), THE FIRST ADDUCTS OF DISELENIUM DINITRIDE [J].

KELLY, PF ;

SLAWIN, AMZ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (16) :1758-1759

[9]

KLAPOTKE TM, 1992, CHEM INORGANIC RING

[10] REACTIONS OF DISULFUR DINITRIDE WITH ANTIMONY PENTACHLORIDE [J].

PATTON, RL ;

JOLLY, WL .

INORGANIC CHEMISTRY, 1969, 8 (07) :1389-&