Synthesis of aromatic aldehydes by laccase-mediator assisted oxidation

被引：78

作者：

Fritz-Langhals, E ^{[1
]}

Kunath, B ^{[1
]}

机构：

[1] Wacker Chem GmbH, Cent Res Co, Consortium Elektrochem Ind GmbH, D-81379 Munchen, Germany

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(98)01215-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic aldehydes can be prepared in aqueous medium by oxidation of the corresponding methyl aromatic compounds in the presence of oxygen, the enzyme laccase and catalytic amounts of various N-hydroxy compounds. Allylic alcohols also gave the corresponding aldehydes in good yield. Competing reactions reveal that the N-hydroxy compound is involved in the rate determining step of the reaction; (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5955 / 5956

页数：2

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