Transfer hydrogenation of nitriles with 2-propanol and Raney® nickel

被引：33

作者：

Mebane, RC ^{[1
]}

Jensen, DR ^{[1
]}

Rickerd, KR ^{[1
]}

Gross, BH ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Chattanooga, TN 37403 USA

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 19期

关键词：

transfer hydrogenation; nitrile reduction; Raney (R) nickel;

D O I：

10.1081/SCC-120023995

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Raney nickel in refluxing 2-propanol containing 2% KOH is an effective catalytic system for reducing nitriles to amines.

引用

页码：3373 / 3379

页数：7

共 33 条

[1]

AKABORI S, 1991, J CHEM SOC P1, P379

[2]

ANDREWS MJ, 1978, INDIAN J CHEM B, V16, P465

[3]

AUGUSTINE RL, 1996, HETEROGENEOUS CATALY, P491

[4] HETEROGENEOUS CATALYTIC TRANSFER HYDROGENATION OF 4-NITRODIPHENYLAMINE TO PARA-PHENYLENEDIAMINES [J].

BANERJEE, AA ;

MUKESH, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (18) :1275-1276

[5]

BERGERON RJ, 1984, SYNTHESIS-STUTTGART, P782

[6]

BESSON M, 1998, Patent No. 5801286

[7] CATALYTIC TRANSFER HYDROGENATION [J].

BRIEGER, G ;

NESTRICK, TJ .

CHEMICAL REVIEWS, 1974, 74 (05) :567-580

[8]

CORDIER G, 1998, Patent No. 5777166

[9] MARKED DIFFERENCES BETWEEN SODIUM-AMMONIA AND CALCIUM-AMMONIA REDUCTION OF NITRILES [J].

DOUMAUX, AR .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (03) :508-&

[10] SYNTHESIS AND CHARACTERIZATION OF LITHIUM AMINOBOROHYDRIDES - A NEW CLASS OF POWERFUL REDUCING AGENTS [J].

FISHER, GB ;

HARRISON, J ;

FULLER, JC ;

GORALSKI, CT ;

SINGARAM, B .

TETRAHEDRON LETTERS, 1992, 33 (32) :4533-4536

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