The crystal structure of [Sm(H2O)5][Ru2(bpy)2(CN)7]•11H2O, a novel mixed d-f coordination polymer

被引：10

作者：

Miller, TA

Jeffery, JC

Ward, MD

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

CRYSTENGCOMM | 2003年 / 5卷

关键词：

D O I：

10.1039/b313122j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication describes the crystal structure of the mixed-metal coordination polymer {[Sm(H2O)5][Ru(CN)(3)-(bpy)-(mu-CN)-Ru(CN)(3)(bpy)].11H(2)O}(infinity), which was isolated in low yield from co-crystallisation of K-2[Ru(bpy)(CN)(4)] with Sm(NO3)(3).6H(2)O. This polymeric chain extends along the a-axis and is constructed from cyanide ligands bridging Ru and Sm metal vertices; it contains both hydrophobic and hydrophilic channels, the latter filled with an H-bonded network of water molecules.

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页码：495 / 497

页数：3

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